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Chemistry

Solutions and Concentration

Solution

A solution is a homogeneous system consisting of two or more components.

Quantity Formula
ω (percent) m(substance) / m(solution) · 100
CM (mol/l) n / V
Dilution m₁ω₁ = m₂ω₂
Saturated ω S / (100 + S) · 100

CM is the molar concentration. n is the amount of substance, V is the volume (l).

Key facts

  • m(solution) = m(substance) + m(solvent). Also m(solution) = ρ · V.
  • Volume (l) is found by dividing the volume in ml by 1000.
  • CM = 10ρω / M (ρ in g/ml, ω in percent).
  • Solubility: S: the saturated amount per 100 g of solvent. That is, the mass of substance dissolved in 100 g of solvent in a saturated solution at a given temperature.
  • There are unsaturated, saturated and supersaturated solutions.
  • As temperature increases, the solubility of solids often increases, while that of gases decreases.

Dilution and mixing

  • During dilution, m(substance) does not change.
  • Mass of added water: m(H₂O) = m₂ − m₁.
  • When mixing solutions, the "cross rule" is used.
  • Crystalline hydrates contain water of crystallization: CuSO₄·5H₂O.

Example: 200 g of a 15% solution contains 30 g of salt.

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